Disable the eyefinity single large screen (sls), they will be cloned which is what you see. Then you need to extend the monitors in ccc.
The problem is that I need the single large screen (spanning) so that I only have a single desktop. The problem is that when running non grouped modes I don't want them to be cloned. It is really piss-poor if the display group has to be un-created every single time that I want to get single monitor output?
Also extended desktop almost never works with the CCC. I select it and it just goes back (same with windows 7 screen resolution panel).